Angel met Giles for the first time in 1.11 Out Of Mind, Out Of Sight (”A vampire in love with a Slayer. It’s rather poetic, in a maudlin sort of way.”) and revealed to the Watcher that he could get copies of the Tiberius Manifesto and the Pergamum Codex, which are key accounts of Slayer lore. The books proved vital to Buffy in 1.12 Prophecy Girl, as Giles discovered in them the prophecy that the Slayer would face the Master and die. In the season four episode of Angel 4.15 Orpheus, Willow was asked by Fred about the Pergamum Codex because it had some interesting stuff in it.
Related episodes: 1.11 Out Of Mind, Out Of Sight, 1.12 Prophecy Girl
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